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Reaction of dimethoxycarbene-DMAD zwitterion with 1,2-diones and anhydrides: A novel synthesis of highly substituted dihydrofurans and spirodihydrofurans

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dc.contributor.author Vijay Nair, G
dc.contributor.author Ani Deepthi
dc.contributor.author Manojkumar, P
dc.contributor.author Bindu, S
dc.contributor.author Sreekumar, V
dc.contributor.author Beneesh, P B
dc.contributor.author Resmi Mohan
dc.contributor.author Suresh, E
dc.date.accessioned 2014-06-17T05:24:17Z
dc.date.available 2014-06-17T05:24:17Z
dc.date.issued 2006
dc.identifier.citation Journal of Organic Chemistry 71(6):2313-2319;17 Mar 2006 en_US
dc.identifier.issn 0022-3263
dc.identifier.uri http://ir.niist.res.in:8080/jspui/handle/123456789/1532
dc.description.abstract The zwitterion formed by the reaction of dimethoxycarbene and DMAD adds efficiently to one of the carbonyl groups of 1,2-dicarbonyl compounds and anhydrides to generate dihydrofurans and spirodihydrofurans in good yields. In many cases, the carbene inserts into the C-C bond of the dione to yield masked vicinal tricarbonyl systems. en_US
dc.language.iso en en_US
dc.publisher American Chemical Society en_US
dc.subject Multicomponent reaction en_US
dc.subject Nucleophilic carbenes en_US
dc.subject Dimethyl butynedioate en_US
dc.subject Facile synthesis en_US
dc.subject Electrophilic styrenes en_US
dc.subject Vinyl isocyanates en_US
dc.subject 4+1 Cycloaddition en_US
dc.subject Derivatives construction en_US
dc.subject Bis(alkylthio)carbenes en_US
dc.title Reaction of dimethoxycarbene-DMAD zwitterion with 1,2-diones and anhydrides: A novel synthesis of highly substituted dihydrofurans and spirodihydrofurans en_US
dc.type Article en_US


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