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Sterically encumbered regioselective cycloaddition of a calixarene derived bis(spirodienone) with 1,2-benzoquinones

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dc.contributor.author Luxmi Varma, R
dc.contributor.author Ganga, V B
dc.contributor.author Suresh, E
dc.contributor.author Suresh, C H
dc.date.accessioned 2015-08-09T12:29:24Z
dc.date.available 2015-08-09T12:29:24Z
dc.date.issued 2006
dc.identifier.citation Tetrahedron Letters 47(6):917-921;6 Feb 2006 en_US
dc.identifier.issn 0040-4039
dc.identifier.uri http://ir.niist.res.in:8080/jspui/handle/123456789/1964
dc.description.abstract A calix[4]arene derived bis(spirodienone) acts as the 2 pi component in a cycloaddition reaction with two molecules of 3,5di-tert-butyl-1-2-benzoquinone in the [2+4] manner leading to macrocycles with a benzodioxin moiety. A theoretical rationalization of the results suggested a sterically encumbered regioselective pathway, which gives sterically crowded products. en_US
dc.language.iso en en_US
dc.publisher Elsevier en_US
dc.subject Diels alder reactions en_US
dc.subject Molecular recognition en_US
dc.subject Upper rim derivatives en_US
dc.subject Calix<4>Arene en_US
dc.title Sterically encumbered regioselective cycloaddition of a calixarene derived bis(spirodienone) with 1,2-benzoquinones en_US
dc.type Article en_US


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