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Stereoselective synthesis of spirocyclopentanones via N-heterocyclic carbene-catalyzed reactions of enals and dienones

Stereoselective synthesis of spirocyclopentanones via N-heterocyclic carbene-catalyzed reactions of enals and dienones

Vijay Nair, G; Beneesh, P B; Sreekumar, V; Suresh, E
URI: http://ir.niist.res.in:8080/jspui/handle/123456789/2099
Date: 2008

Abstract:

Homoenolates generated from enals by nucleophilic heterocyclic carbene (NHC) catalysis undergo a conjugate addition/cyclization sequence with cyclic dienones, culminating in the efficient synthesis of spirocyclopentanones.

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