Palladium catalyzed ring opening of azabicyclic olefins with organoindium and gallium reagents: a facile access towards benzylated cyclopentanoids

dc.contributor.author	Jubi John
dc.contributor.author	Adarsh, B
dc.contributor.author	Radhakrishnan, K V
dc.date.accessioned	2016-01-18T06:59:52Z
dc.date.available	2016-01-18T06:59:52Z
dc.date.issued	2010
dc.identifier.citation	Tetrahedron 66(6):1383-1388;06 Feb 2010	en_US
dc.identifier.issn	0040-4020
dc.identifier.uri	http://ir.niist.res.in:8080/jspui/handle/123456789/2108
dc.description.abstract	Palladium catalyzed desymmmetrization of diazabicyclic olefins with organoindium and gallium reagents were examined These reactions provided an easy access to trans-3,4-disubstituted cyclopentenes in good to excellent yields Indium reagents exhibited better reactivity compared to gallium reagents The developed methodology demonstrates a simple. clean and efficient route towards substituted cyclopentenes The present strategy provides access to benzylated cyclopentene derivatives in one pot, which forms the skeleton of a number of biologically important molecules	en_US
dc.language.iso	en	en_US
dc.publisher	Elsevier	en_US
dc.subject	Meso bicyclic hydrazines	en_US
dc.subject	Carbon bond formation	en_US
dc.subject	Functionalized cyclopentenes	en_US
dc.subject	Stereoselective-synthesis	en_US
dc.subject	Alkylidene cyclopentenes	en_US
dc.subject	Enantioselective desymmetrization	en_US
dc.subject	Allylation	en_US
dc.subject	Indium	en_US
dc.title	Palladium catalyzed ring opening of azabicyclic olefins with organoindium and gallium reagents: a facile access towards benzylated cyclopentanoids	en_US
dc.type	Article	en_US