Browsing 2011 by Subject "Phosphine-ligands"

Now showing items 1-3 of 3

Assessment of stereoelectronic effects in grubbs first-generation olefin metathesis catalysis using molecular electrostatic potential

Jomon Mathew; Suresh, C H (American Chemical Society, 2011)

Quantum mechanically derived molecular electrostatic potential (MESP) based descriptors have been proposed for the assessment of both the steric and electronic effects of phosphines in several first-generation Grubbs olefin ...
Assessment of steric and electronic effects of n-heterocyclic carbenes in grubbs olefin metathesis using molecular electrostatic potential

Jomon Mathew; Suresh, C H (American Chemical Society, 2011)

The steric and electronic effects of N-heterocyclic carbenes in the second-generation Grubbs olefin metathesis catalysts are quantified on the basis of molecular electrostatic potential at the carbene carbon of both the ...
Mechanisms of reductive eliminations in square planar pd(ii) complexes: Nature of eliminated bonds and role of trans influence

Sajith, P K; Suresh, C H (American Chemical Society, 2011)

The trans influence of various phosphine ligands (L) in direct as well as dissociative reductive elimination pathways yielding CH(3)CH(3) from Pd(CH(3))(2)L(2) and CH(3)Cl from Pd(CH(3))(Cl)L(2) has been quantified in terms ...

Now showing items 1-3 of 3

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