Synthesis of novel ferrocenyl N/O-heterocycles, chiral P,N-ligand and alpha-dehydro-beta-amino acid derived short peptides from Morita-Baylis-Hillman adducts of ferrocenealdehyde

Abstract

The ‘golden triangle’ of Fc,OH/NH, COOmoieties created by classical/ aza-MBH reaction of ferrocenealdehyde has been exploited for the first time for the synthesis of novel multisubstituted ferrocenyl N/O heterocycles, chiral P,N ligands and ferrocenyl a-dehydro-b-peptides