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Pd-catalyzed C-N coupling of vinylbromides and sulfonimidamides: A facile synthesis of N-vinylsulfonimidamides

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dc.contributor.author Nandi, G C
dc.contributor.author Kota, S R
dc.contributor.author Wakchaure, P B
dc.contributor.author Chinthakindi, P K
dc.contributor.author Govender, T
dc.contributor.author Kruger, H G
dc.contributor.author Naicker, T
dc.contributor.author Arvidsson, P I
dc.date.accessioned 2016-07-14T10:03:30Z
dc.date.available 2016-07-14T10:03:30Z
dc.date.issued 2015
dc.identifier.citation RSC Advances 5(76):62084-62090; 2015 en_US
dc.identifier.uri http://hdl.handle.net/123456789/2353
dc.description.abstract N0-Vinyl sulfonimidamides have been synthesized through a Pd-catalyzed C–N cross coupling between the N0-(imine nitrogen) of N0-deprotected sulfonimidamides and vinyl bromides. The hitherto unreported products were obtained in moderate to excellent yield, and the C–C double bond geometry of the vinylic substrates were retained during the course of reaction. Single crystal X-ray crystallographic analysis confirmed the product structure. Furthermore, we demonstrate that the formed N0-vinyl sulfonimidamides could undergo hydrogenation with Pd–C/H2 to provide N0-alkyl sulfonimidamides en_US
dc.language.iso en en_US
dc.publisher Royal Society of Chemistry en_US
dc.title Pd-catalyzed C-N coupling of vinylbromides and sulfonimidamides: A facile synthesis of N-vinylsulfonimidamides en_US
dc.type Article en_US


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