Triazatruxene Radical Cation: A Trigonal Class III Mixed Valence System

dc.contributor.author	Thomas, T G
dc.contributor.author	Chandra Shekar, S
dc.contributor.author	Swathi, R S
dc.contributor.author	Gopidas, K R
dc.date.accessioned	2018-06-19T11:29:13Z
dc.date.available	2018-06-19T11:29:13Z
dc.date.issued	2017-01-03
dc.identifier.citation	RSC Advances, 7(2):821-825	en_US
dc.identifier.uri	http://10.10.100.66:8080/xmlui/handle/123456789/3113
dc.description.abstract	The highly symmetric and stable triazatruxene radical cation was generated chemically for the first time. The intervalence charge transfer (IV-CT) absorption band of the radical cation was observed at 7500–12 500 cm 1. The IV-CT band exhibited a well-resolved, solvent independent vibrational structure which prompted us to classify the radical cation as a Robin and Day class III IV-CT compound. The assignment was examined in light of two previously reported semiclassical models for three-center IV-CT systems. The triazatruxene radical cation is the first and only example of a three-center class III IVCT system.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.title	Triazatruxene Radical Cation: A Trigonal Class III Mixed Valence System	en_US
dc.type	Article	en_US