dc.contributor.author |
Elool Dov, N |
|
dc.contributor.author |
Sreejith, S |
|
dc.contributor.author |
Cohen, D |
|
dc.contributor.author |
Bendikov, T |
|
dc.contributor.author |
Rechav, K |
|
dc.contributor.author |
Linda, J W S |
|
dc.contributor.author |
Lahav, M |
|
dc.contributor.author |
Van Der Boom, M E |
|
dc.date.accessioned |
2018-06-21T05:51:19Z |
|
dc.date.available |
2018-06-21T05:51:19Z |
|
dc.date.issued |
2017-07-13 |
|
dc.identifier.citation |
Journal of the American Chemical Society, 139(33):11471-11481 |
en_US |
dc.identifier.uri |
http://10.10.100.66:8080/xmlui/handle/123456789/3118 |
|
dc.description.abstract |
In this study, we demonstrate a versatile approach for the formation of electrochromic nanoscale assemblies on
transparent conductive oxides on both rigid and flexible substrates. Our method is based on the application of alternating spin-coated layers of well-defined metal polypyridyl complexes and a palladium(II) salt to form electrochemically addressable films with a high chromophore density. By varying the central metal ion of the polypyridyl complexes (Os, Ru, and Fe) and their ligands and by mixing these complexes, coatings with a wide range of colors can be achieved. These coatings cover a large area of RGB color space. The coloration intensities of these nanoscale films can be tuned by the number of deposition steps. The materials have very
attractive ON/OFF ratios, electrochemical stabilities, and coloration efficiencies. Reversible color-to-colorless and color-to-color transitions were demonstrated, and the films were further integrated into sandwich cells. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
American Chemical Society |
en_US |
dc.title |
Electrochromic Metallo-Organic Nanoscale Films: Fabrication, Color Range, and Devices |
en_US |
dc.type |
Article |
en_US |