Meso-Aryl [20]p Homoporphyrin: The Simplest Expanded Porphyrin with the Smallest Mçbius Topology

dc.contributor.author	Anju, K S
dc.contributor.author	Mainak Das
dc.contributor.author	Adinarayana, B
dc.contributor.author	Suresh, C H
dc.contributor.author	Srinivasan, A
dc.date.accessioned	2018-07-24T05:57:53Z
dc.date.available	2018-07-24T05:57:53Z
dc.date.issued	2017-12-04
dc.identifier.citation	Angewandte Chemie - International Edition, 56(49):15667–15671	en_US
dc.identifier.uri	http://10.10.100.66:8080/xmlui/handle/123456789/3193
dc.description.abstract	An unstable conjugated homoporphyrin was successfully stabilized by introducing meso-aryl substitutents. It was evident from the moderate diatropic ring current found by NMR analysis that the newly formed 20p conjugated free base and its protonated form exhibited Mçbius aromatic character. Furthermore, complexation as a ligand with an RhI ion afforded a unique binding mode and retained the Mçbius aromaticity. Overall, these compounds are the smallest Mçbius aromatic molecules, as confirmed by spectral and crystalstructure analysis and supported by theoretical studies.	en_US
dc.language.iso	en	en_US
dc.publisher	Wiley	en_US
dc.subject	conjugation	en_US
dc.subject	coordination chemistry	en_US
dc.subject	homoporphyrins	en_US
dc.subject	Mçbius aromaticity	en_US
dc.subject	porphyrinoids	en_US
dc.title	Meso-Aryl [20]p Homoporphyrin: The Simplest Expanded Porphyrin with the Smallest Mçbius Topology	en_US
dc.type	Article	en_US