Catalyst-Controlled Dual Reactivity of Sulfonimidamides: Synthesis of Propargylamines and N-Propargyl Sulfonimidamides

dc.contributor.author	Irfana Jesin, C P
dc.contributor.author	Nandi, G C
dc.date.accessioned	2019-07-02T09:53:39Z
dc.date.available	2019-07-02T09:53:39Z
dc.date.issued	2019-01-14
dc.identifier.citation	Chemistry - A European Journal; 25:743-749	en_US
dc.identifier.uri	https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201805000
dc.identifier.uri	http://10.10.100.66:8080/xmlui/handle/123456789/3386
dc.description.abstract	Sulfonimidamides (SIAs) are acting both as surrogate amines and nucleophiles depending on the reaction conditions to access propargylamines and N‐propargyl SIAs, respectively. The amine part of SIAs has been cleaved in an InCl3‐catalyzed three‐component A3 coupling reaction with aldehyde and acetylene to yield propargylamine. Moreover, N‐propargyl SIAs were obtained via the direct‐imination of propargyl alcohols in the presence of BF3⋅OEt2.	en_US
dc.language.iso	en	en_US
dc.publisher	Wiley	en_US
dc.subject	amines	en_US
dc.subject	sulfonimidamides	en_US
dc.subject	sulfur	en_US
dc.subject	surrogate amine	en_US
dc.subject	synthetic methods	en_US
dc.title	Catalyst-Controlled Dual Reactivity of Sulfonimidamides: Synthesis of Propargylamines and N-Propargyl Sulfonimidamides	en_US
dc.type	Article	en_US