Catalyst-Controlled Dual Reactivity of Sulfonimidamides: Synthesis of Propargylamines and N-Propargyl Sulfonimidamides

dc.contributor.author	Irfana Jesin, C P
dc.contributor.author	Nandi, G C
dc.date.accessioned	2019-07-19T14:40:31Z
dc.date.available	2019-07-19T14:40:31Z
dc.date.issued	2019-01-15
dc.identifier.citation	Chemistry – A European Journal; 25(3):743 –749	en_US
dc.identifier.uri	https://onlinelibrary.wiley.com/doi/full/10.1002/chem.201805000
dc.identifier.uri	http://10.10.100.66:8080/xmlui/handle/123456789/3426
dc.description.abstract	Sulfonimidamides (SIAs) are acting both as surrogate amines and nucleophiles depending on the reaction conditions to access propargylamines and N-propargyl SIAs, respectively. The amine part of SIAs has been cleaved in an InCl3-catalyzed three-component A3 coupling reaction with aldehyde and acetylene to yield propargylamine. Moreover, N-propargyl SIAs were obtained via the direct-imination of propargyl alcohols in the presence of BF3·OEt2.	en_US
dc.language.iso	en	en_US
dc.publisher	Wiley	en_US
dc.subject	amines	en_US
dc.subject	sulfonimidamides	en_US
dc.subject	sulfur	en_US
dc.subject	surrogate amine	en_US
dc.subject	synthetic methods	en_US
dc.title	Catalyst-Controlled Dual Reactivity of Sulfonimidamides: Synthesis of Propargylamines and N-Propargyl Sulfonimidamides	en_US
dc.type	Article	en_US