Homocarbaporphyrinoids: The m-o-m and p-o-p Terphenyl Embedded Expanded Porphyrin Analogues and Their RhI Complexes

dc.contributor.author	Adinarayana, B
dc.contributor.author	Das, M
dc.contributor.author	Suresh, C H
dc.contributor.author	Srinivasan, A
dc.date.accessioned	2019-07-22T15:19:57Z
dc.date.available	2019-07-22T15:19:57Z
dc.date.issued	2019-03-27
dc.identifier.citation	Chemistry; 25(18):4683-4687	en_US
dc.identifier.uri	https://onlinelibrary.wiley.com/doi/10.1002/chem.201900495
dc.identifier.uri	http://10.10.100.66:8080/xmlui/handle/123456789/3444
dc.description.abstract	Stable homocarbaporphyrinoids were successfully synthesized by incorporating the m-o-m and p-o-p terphenyl units into the porphyrin core. The distinct bonding modes of terphenyl in the macrocycle generated two structural isomers with two and four carbon atoms in the macrocyclic environment. The core was utilized to stabilize the RhI ion. The spectral and structural analyses revealed that the restricted (m-o-m) and allowed (p-o-p) conjugation in the macrocyclic core provide overall non-aromatic characteristics both to the free bases and their complexes.	en_US
dc.language.iso	en	en_US
dc.publisher	Wiley	en_US
dc.subject	coordination chemistry	en_US
dc.subject	porphyrins	en_US
dc.subject	porphyrinoids	en_US
dc.subject	non-aromaticity	en_US
dc.title	Homocarbaporphyrinoids: The m-o-m and p-o-p Terphenyl Embedded Expanded Porphyrin Analogues and Their RhI Complexes	en_US
dc.type	Article	en_US