Suresh, C H; Frenking, G
(American Chemical Society, 2012-10-22)
The formation of metallacyclobutadienes (MCBs
from chloro-ligated alkylidyne complexes of group 4, 5, and 6 transition metals (MCln(C3H3)) has been studied at the BP86/
def2-TZVPP level. All the MCBs showed M−Cβ distances ...