dc.contributor.author |
R, Joseph |
|
dc.contributor.author |
A, Asok |
|
dc.contributor.author |
K, Joseph |
|
dc.date.accessioned |
2020-02-26T09:33:17Z |
|
dc.date.available |
2020-02-26T09:33:17Z |
|
dc.date.issued |
2019-07-16 |
|
dc.identifier.citation |
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy; 224:117390 |
en_US |
dc.identifier.uri |
https://reader.elsevier.com/reader/sd/pii/S1386142519307802?token=DFDD56F104F0E22DE384574FA71845C924EC6306A58DDCF6EE7F35D2C978E6357B0092F2CB741EFACD060CDF8170D2FA |
|
dc.identifier.uri |
http://10.10.100.66:8080/xmlui/handle/123456789/3613 |
|
dc.description.abstract |
A quinoline functionalized pillar[5]arene, QPA has been prepared and its interaction with biologically relevant ions and molecules in aqueous solution has been demonstrated. The sensor molecule, QPA has shown selectivity towards Fe3+ among eleven metal ions studied. The Fe3+ complex of QPA (FeQPA) selectively interacts with F– among halides by ~4 fold fluorescence enhancement. Further, FeQPA has shown selectivity towards arginine and lysine among twenty naturally occurring amino acids. The binding of QPA with Fe3+ has been confirmed by MALDI-TOF and 1H NMR titrations. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
ScienceDirect |
en_US |
dc.subject |
Amino acid detection |
en_US |
dc.subject |
Fe(3+) sensor |
en_US |
dc.subject |
Fluorescence |
en_US |
dc.subject |
Fluoride sensor |
en_US |
dc.subject |
Pillar[5]arene |
en_US |
dc.title |
Quinoline Appended Pillar[5]arene (Qpa) as Fe3+ Sensor and Complex of Fe3+ (Feqpa) as a Selective Sensor for F-, Arginine and Lysine in the Aqueous Medium. |
en_US |
dc.type |
Article |
en_US |