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Multicomponent reactions based on nucleophilic carbenes and their applications in organic synthesis

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dc.contributor.author Vijay Nair, G
dc.contributor.author Rajeev S Menon
dc.contributor.author Sreekumar, V
dc.date.accessioned 2021-02-08T13:32:23Z
dc.date.available 2021-02-08T13:32:23Z
dc.date.issued 2005
dc.identifier.citation Pure and Applied Chemistry 77(7):1191-1198; Jul 2005 en_US
dc.identifier.issn 0033-4545
dc.identifier.uri http://hdl.handle.net/123456789/3665
dc.description.abstract Zwitterionic intermediates generated from the addition of nonprotic nucleophiles to activated acetylenes are intercepted with various third components constituting novel multicomponent organic transformations. Catalytic amounts of an organic base like pyridine were found to trigger reactions between an electrophilic acetylene and a variety of electrophiles. The reactions proceed through dipolar intermediates and show high stereoselectivity. en_US
dc.language.iso en en_US
dc.publisher Walter de Gruyter en_US
dc.subject Carbenes en_US
dc.subject Multicomponent reactions en_US
dc.subject Isocyanides en_US
dc.subject Dipoles en_US
dc.subject Zwitterions en_US
dc.title Multicomponent reactions based on nucleophilic carbenes and their applications in organic synthesis en_US
dc.type Article en_US


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