Room temperature synthesis of high temperature stable lanthanum phosphate–yttria nano composite

Abstract

A facile aqueous sol–gel route involving precipitation–peptization mechanism followed by electrostatic stabilization is used for synthesizing nanocrystalline composite containing lanthanum phosphate and yttria. Lanthanum phosphate (80 wt%)–yttria (20 wt%) nano composite (LaPO4–20%Y2O3), has an average particle size of 70 nm after heat treatment of precursor at 600 8C. TG–DTA analysis reveals that stable phase of the composite is formed on heating the precursor at 600 8C. The TEM images of the composite show rod shape morphology of LaPO4 in which yttria is acquiring near spherical shape. Phase identification of the composite as well as the phase stability up to 1300 8C was carried out using X-ray diffraction technique. With the phases being stable at higher temperatures, the composite synthesized should be a potential material for high temperature applications like thermal barrier coatings and metal melting applications