Joseph, J; Jaroschik, F; Radhakrishnan, K V; Vasse, Jean-Luc; Szymoniak, J
(Royal Society of Chemistry, 2013)
Allyltitanocene complexes can be generated by reacting pentafulvenes with DIBAL-H and Cp2TiCl2. Their coupling with aldehydes affords homoallylic alcohols in a highly regio- and stereoselective manner. The potential of ...