Pentafulvene-derived η3-allyltitanocenes as intermediates for the stereoselective functionalization of 5-membered carbocycles.

dc.contributor.author	Joseph, J
dc.contributor.author	Jaroschik, F
dc.contributor.author	Radhakrishnan, K V
dc.contributor.author	Vasse, Jean-Luc
dc.contributor.author	Szymoniak, J
dc.date.accessioned	2013-08-19T06:22:29Z
dc.date.available	2013-08-19T06:22:29Z
dc.date.issued	2013
dc.identifier.citation	Chemical Communications 49(40):4549-4551;2013	en_US
dc.identifier.uri	http://hdl.handle.net/123456789/579
dc.description.abstract	Allyltitanocene complexes can be generated by reacting pentafulvenes with DIBAL-H and Cp2TiCl2. Their coupling with aldehydes affords homoallylic alcohols in a highly regio- and stereoselective manner. The potential of this method for the stereoselective synthesis of cyclopentane derivatives is illustrated.	en_US
dc.language.iso	en	en_US
dc.publisher	Royal Society of Chemistry	en_US
dc.subject	Fischer carbene complexes	en_US
dc.subject	6+3 Cycloaddition	en_US
dc.subject	Crystal-structure	en_US
dc.subject	7-Membered ring	en_US
dc.subject	Aldol reactions	en_US
dc.title	Pentafulvene-derived η3-allyltitanocenes as intermediates for the stereoselective functionalization of 5-membered carbocycles.	en_US
dc.type	Article	en_US