dc.contributor.author |
George, S C |
|
dc.contributor.author |
Sreeja, T |
|
dc.contributor.author |
Anas, S |
|
dc.contributor.author |
Radhakrishnan, K V |
|
dc.contributor.author |
Yamamoto, Y |
|
dc.date.accessioned |
2013-11-13T06:23:40Z |
|
dc.date.available |
2013-11-13T06:23:40Z |
|
dc.date.issued |
2011 |
|
dc.identifier.citation |
Organic Letters 13(19):4984-4987;07 Oct 2011 |
en_US |
dc.identifier.issn |
1523-7060 |
|
dc.identifier.uri |
http://ir.niist.res.in:8080/jspui/handle/123456789/737 |
|
dc.description.abstract |
The palladium catalyzed 1, 8-conjugate addition of heptafulvene, an antiaromatic conjugated 8 pi-electron system, is discussed. The method is utilized for the concise synthesis of bis-functionalized cycloheptatriene (CHT) derivatives. This is the first report on the palladium catalyzed bisfunctionalization of a cyclic cross conjugated system. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
American Chemical Society |
en_US |
dc.subject |
Activated olefins |
en_US |
dc.subject |
Cycloaddition reactions |
en_US |
dc.subject |
Alpha-allylation |
en_US |
dc.subject |
8-Cyanoheptafulvene |
en_US |
dc.subject |
8, 8-Dicyano-3-(4'-N, N-Dimethylamino) Phenylheptafulvene |
en_US |
dc.subject |
1, 6-Addition |
en_US |
dc.subject |
Benzyne |
en_US |
dc.title |
Palladium catalyzed 1, 8-conjugate addition to heptafulvene via bis-pi-allyl palladium complexes |
en_US |
dc.type |
Article |
en_US |