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Palladium catalyzed tandem ring opening-ring closing reaction of diazabicyclic alkenes: A facile one pot strategy for cyclopentannulation of heterocycles

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dc.contributor.author Jubi John
dc.contributor.author Indu, U
dc.contributor.author Suresh, E
dc.contributor.author Radhakrishnan, K V
dc.date.accessioned 2013-11-22T09:31:01Z
dc.date.available 2013-11-22T09:31:01Z
dc.date.issued 2009
dc.identifier.citation Journal of the American Chemical Society 131(14):5042-5043;15 Apr 2009 en_US
dc.identifier.issn 0002-7863
dc.identifier.uri http://ir.niist.res.in:8080/jspui/handle/123456789/822
dc.description.abstract A novel palladium catalyzed protocol for the synthesis of cyclopentene fused heterocycles from diazabicyclic alkenes and ortho-functionalized aryliodides has been elaborated. The reaction can be tuned toward the formation of either 3,4-disubstituted cyclopentenes or cyclopentene fused heterocycles by careful manipulation of the reaction parameters. A number of cyclopentene fused benzofurans and indole derivatives were prepared in excellent yield by utilizing the developed methodology en_US
dc.language.iso en en_US
dc.publisher American Chemical Society en_US
dc.subject Bicyclic hydrazines en_US
dc.subject Functionilized cyclopentenes en_US
dc.subject Stereoselective synthesis en_US
dc.subject Cyclopentadiene en_US
dc.subject Prostacyclin en_US
dc.subject Arylation en_US
dc.subject Enantioselective desymmetrization en_US
dc.title Palladium catalyzed tandem ring opening-ring closing reaction of diazabicyclic alkenes: A facile one pot strategy for cyclopentannulation of heterocycles en_US
dc.type Article en_US


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